Surface-coated AlF3 nanolayers enable polysulfide confinement within biomass-derived nitrogen-doped hierarchical porous carbon microspheres for improved lithium-sulfur batteries

Zhenya Luo; Yaqin Wu; Xupeng Xu; Wenqi Ju; Weixin Lei; Dazhuan Wu; Junan Pan; Xiaoping Ouyang

doi:10.1016/j.jcis.2024.01.123

Surface-coated AlF₃ nanolayers enable polysulfide confinement within biomass-derived nitrogen-doped hierarchical porous carbon microspheres for improved lithium-sulfur batteries

J Colloid Interface Sci. 2024 Apr 15:660:657-668. doi: 10.1016/j.jcis.2024.01.123. Epub 2024 Jan 20.

Authors

Zhenya Luo¹, Yaqin Wu², Xupeng Xu², Wenqi Ju², Weixin Lei², Dazhuan Wu³, Junan Pan⁴, Xiaoping Ouyang⁵

Affiliations

¹ College of Energy Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China; School of Materials Science and Engineering, Xiangtan University, Xiangtan, Hunan 411105, China.
² School of Materials Science and Engineering, Xiangtan University, Xiangtan, Hunan 411105, China.
³ College of Energy Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China. Electronic address: wudazhuan@zju.edu.cn.
⁴ School of Materials Science and Engineering, Xiangtan University, Xiangtan, Hunan 411105, China. Electronic address: pja3330@xtu.edu.cn.
⁵ College of Energy Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China; School of Materials Science and Engineering, Xiangtan University, Xiangtan, Hunan 411105, China. Electronic address: oyxp2003@aliyun.com.

PMID: 38271802
DOI: 10.1016/j.jcis.2024.01.123

Abstract

The electrically insulating and volumetric deformation of sulfur and the shuttle effect of the intermediate lithium polysulfide (LiPSs) have severely hindered the development of lithium-sulfur batteries (LSBs). Herein, a synergistic strategy of hierarchical porous nitrogen-doped carbon microspheres (PNCM) derived from low-cost biomass with surface-coated AlF₃ nanolayer as a multifunctional sulfur host (denoted as PNCM@S@AlF₃) was developed. The PNCM not only possesses an abundant pore structure, large surface area, and high electrical conductivity but also features an intrinsic N-doped and fluorinated framework, which effectively enhances the physical adsorption and chemical anchoring to LiPSs. In addition, the AlF₃ nanolayer protects the open surface of the porous carbon to isolate sulfur species from the electrolyte to reduce irreversible losses while accelerating the redox kinetics of LiPSs through strong polar adsorption and bonding. Hence, the PNCM@S@AlF₃ cathode exhibits an initial capacity as high as 1176.2 mAh/g at 0.2C, and the cycling stability and rate capability are superior to that of PNCM@S without AlF₃ coating. Impressively, the PNCM@S@AlF₃ cathode delivers stable long-term cycling performance at a high rate of 2C, with 95.6% capacity retention after 500 cycles. This work presents a facile, sustainable, and efficient synergistic strategy for developing advanced LSBs.

Keywords: AlF(3) coating; Biomass-derived carbon; Hierarchical porous; Lithium-sulfur batteries; Synergistic effect.