From C4H7N2Ge0.4Sn0.6Br3 to C6H11N2Ge0.4Sn0.6Br3: Effective Modulation of the Second Harmonic Generation Effect and Optical Band Gap by Planar π-Conjugated Organic Cation Size

Yuwei Kang; Can Yang; Jie Gou; Yaolong Zhu; Qingwen Zhu; Qi Wu

doi:10.1021/acs.inorgchem.3c04148

From C₄H₇N₂Ge_0.4Sn_0.6Br₃ to C₆H₁₁N₂Ge_0.4Sn_0.6Br₃: Effective Modulation of the Second Harmonic Generation Effect and Optical Band Gap by Planar π-Conjugated Organic Cation Size

Inorg Chem. 2024 Feb 5;63(5):2725-2731. doi: 10.1021/acs.inorgchem.3c04148. Epub 2024 Jan 21.

Authors

Yuwei Kang^{1

2}, Can Yang¹, Jie Gou¹, Yaolong Zhu¹, Qingwen Zhu¹, Qi Wu¹

Affiliations

¹ State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan 430200, China.
² Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi 435002, China.

PMID: 38247137
DOI: 10.1021/acs.inorgchem.3c04148

Abstract

In the search for nonlinear optical (NLO) materials with excellent overall performance, we have devoted ourselves to organic-inorganic hybrids consisting of anionic groups containing stereochemically active lone-pair (SCALP) electron cations and organic planar π-conjugated group cations. Accordingly, in this paper, two novel organic-inorganic hybrid metal halides, C₄H₇N₂Ge_0.4Sn_0.6Br₃ (I) and C₆H₁₁N₂Ge_0.4Sn_0.6Br₃ (II), have been synthesized. The powder second-harmonic technique shows that both C₄H₇N₂Ge_0.4Sn_0.6Br₃ and C₆H₁₁N₂Ge_0.4Sn_0.6Br₃ have moderately strong second-order nonlinear optical effects, which are about 2.03 (I) and 1.16 (II) times that of KH₂PO₄ (KDP), respectively. They also have different optical band gaps of 2.75 (I) and 2.88 eV (II) due to the different sizes of the organic cations, and their photoluminescent and thermal properties were also investigated. This work provides new structural insights for the design and modulation of organic-inorganic hybrid halide materials with multiple excellent optical properties.