Transformation of cereal grains: Botanical and chemical analysis of food residues encrusted on pottery from the Funnel Beaker settlement of Oldenburg LA 77, northern Germany

PLoS One. 2024 Jan 19;19(1):e0296986. doi: 10.1371/journal.pone.0296986. eCollection 2024.

Abstract

An integrated botanical and chemical approach is used to study surface residues on Funnel Beaker ceramics from the site of Oldenburg LA 77, in northern Germany. Organic residues were discovered adhering to fragments of thick-walled, undecorated ceramic vessels (n = 19) and ceramic discs (n = 2). The surface residues were studied using scanning electron microscopy (SEM), to examine remains of cereals and other plant tissues that survived food preparation and cooking, and using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and direct time-resolved mass spectrometry (DTMS), to chemically identify specific food components. The SEM results show a reoccurring presence of cereal grain (emmer and barley) and one case of co-occurrence of emmer and fat-hen seeds. The SEM evidence for the use of sprouted emmer grain and milk-ripe barley from the Oldenburg residues greatly enhances our understanding of Neolithic foodways in northwestern Europe. The ATR-FTIR results showed that roughly a third of the surface residues contain traces of the original foods prepared or processed and DTMS results confirm that most of the residues primarily contain polysaccharides and a minimal amount of plant protein and that they lack lipids. Only one residue presents minor indications for a (partly) animal origin. The ceramic vessels were thus used almost exclusively for the processing or cooking of cereal grains. This study offers an intimate view of the cuisine and cooking practices (and in some cases their seasonal timing) in an early agricultural village located in a marginal farming region on the south coast of the Baltic Sea.

MeSH terms

  • Animals
  • Ceramics / chemistry
  • Chickens*
  • Edible Grain* / chemistry
  • Female
  • Gas Chromatography-Mass Spectrometry
  • Germany

Grants and funding

The authors Johannes Müller (JM) and Wiebke Kirleis (WK) were both supported through funds by the German Research Foundation (Deutsche Forschungsgemeinschaft, DFG) within the two programs: A) Collaborative Research Centre 1266 'Scales of Transformation – Human-Environmental Interaction in Prehistoric and Archaic Societies', Project number 290391021 – SFB 1266) and B) Cluster of Excellence 'ROOTS – Social, Environmental, and Cultural Connectivity in Past Societies' (project ref. 390870439—EXC 2150). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.