Triplet transitions of light-emitting materials, including rose bengal, tris(2-phenylpyridine)iridium(III) [Ir(ppy)3], tris(1-phenylisoquinoline)iridium(III) [Ir(piq)3], and bis[2-(4,6-difluorophenyl)pyridinato-C2,N](picolinato)iridium(III) (FIrpic), were studied using step-scan time-resolved Fourier-transform near-infrared spectroscopy. The samples were excited to their singlet excited states by a 355 nm laser and then underwent efficient conversions/crossings to their triplet manifolds. For rose bengal, a transient absorption band appeared at 9400 cm-1, attributed to the T3 ← T1 transition based on the corresponding time evolution and the theoretical calculations. For Ir(ppy)3, Ir(piq)3, and FIrpic, the most intense bands were observed at 7700, 7500, and 7500 cm-1 and assigned to T7 ← T1, T6 ← T1, and T6 ← T1 transitions, respectively. For Ir(ppy)3, the most intense band involved transitions between different triplet metal-to-ligand charge transfer (3MLCT) states, while for Ir(piq)3 and FIrpic, they involved a metal center to 3MLCT transition. These T1 states were assigned to 3MLCT.