Adsorbents prepared from epoxy-based porous materials of microcrystalline cellulose for excellent adsorption of anionic and cationic dyes

Int J Biol Macromol. 2024 Mar;260(Pt 1):129477. doi: 10.1016/j.ijbiomac.2024.129477. Epub 2024 Jan 16.

Abstract

It reported a porous material prepared from microcrystalline cellulose (MCC), to achieve rapid preparation of adsorbents. The porous material was characterized by several tools including 1H NMR, FTIR, XPS, and SEM. Two adsorbents were prepared and subjected to adsorption experiments. Dye adsorption experiments show that the adsorption driving is electrostatic interactions and the process is chemisorption. The maximum capacity of Microcrystalline cellulose-g-Poly (glycidyl methacrylate)-Tannins (MPT) reached 191.3 (Methylene blue), 123.7 mg g-1 (Rhodamine B), and Microcrystalline cellulose-g-Poly (glycidyl methacrylate)-Lysine (MPL) attained 425.8 (Methylene blue), 480.7 mg g-1 (Methyl orange). The results were followed the pseudo-second-order (PSO) and agreed with the Langmuir fit model. Adsorption-desorption cycling experiments further indicate that the adsorbent possesses outstanding reproducibility. At last, epoxidized bio-porous materials are positive in the preparation of dye adsorbents with critical adsorption properties.

Keywords: Dye adsorption; Epoxy-functionalized; Microcrystalline cellulose.

MeSH terms

  • Adsorption
  • Cations
  • Cellulose*
  • Coloring Agents* / chemistry
  • Epoxy Compounds*
  • Kinetics
  • Methacrylates*
  • Methylene Blue / chemistry
  • Porosity
  • Reproducibility of Results
  • Water Pollutants, Chemical* / chemistry

Substances

  • Coloring Agents
  • microcrystalline cellulose
  • glycidyl methacrylate
  • Methylene Blue
  • Cations
  • Water Pollutants, Chemical
  • Cellulose
  • Epoxy Compounds
  • Methacrylates