In this study, antioxidant, and antimicrobial starch-based biocomposite films reinforced with coffee husks (S/CH) were developed by incorporating either limonene (LM) (S/CH/LM) or its oligomer derivative, poly(limonene) (PLM) (S/CH/PLM), at different concentrations (5-10 % w/w of starch). Through a comprehensive assessment of film properties, morphology, and structure, a comparative analysis between the two additives was proposed. Scanning electron microscopy (SEM) revealed some defects throughout the polymer matrix after additive incorporation. The tensile strength (TS) and modulus of elasticity (ME) showed a decrease upon the inclusion of both LM and PLM, while the elongation at break (E) increased. Notably, PLM exhibited outstanding antioxidant capacity, enhancing the films by 108 % over control samples. Additionally, at just 5 % concentration, PLM effectively inhibited the growth of Escherichia coli ATCC 11775 (35.33 ± 2.52 mm) and demonstrated an impressive UV-Vis barrier, comparable to the highest amount of LM incorporated. Therefore, this research highlights the potential of coffee husk-reinforced starch biocomposites with limonene-derived additives as a promising solution for food packaging applications. The comparative analysis sheds light on the advantages of using the PLM in terms of antioxidant and antimicrobial properties, contributing to the advancement of active packaging technologies.
Keywords: Active packaging; Biopolymers; Terpenes.
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