Characterization of Methane Extraction during ScCO2-ECBM: Consideration of Competitive Adsorption of ScCO2 and CH4

Zhiquan Wang; Zhengdong Liu; Ze Hu

doi:10.1021/acsomega.3c08043

Characterization of Methane Extraction during ScCO₂-ECBM: Consideration of Competitive Adsorption of ScCO₂ and CH₄

ACS Omega. 2023 Dec 27;9(1):1591-1602. doi: 10.1021/acsomega.3c08043. eCollection 2024 Jan 9.

Authors

Zhiquan Wang^{1

2}, Zhengdong Liu³, Ze Hu³

Affiliations

¹ College of Safety Science and Engineering, Liaoning Technical University, Fuxin 123000, China.
² State Key Laboratory of Coal Mine Safety Technology, China Coal Technology & Engineering Group Shenyang Research Institute, Fushun 113122, China.
³ Center for Rock Instability and Seismicity Research, School of Resource and Civil Engineering, Northeastern University, Shenyang 110819, China.

Abstract

The supercritical CO₂ enhanced coalbed methane (ScCO₂-ECBM) technology is still in the development stage, and many simulation experiments and theoretical studies related to ScCO₂-ECBM are being improved. Previous research works have conducted many studies on the competitive adsorption of CO₂ and CH₄ in coal, but there is less research on the competitive adsorption of ScCO₂ and CH₄ and its impact on methane extraction characteristics. In this study, a permeability model considering the competitive effects of effective stress and adsorption swelling on permeability was established. Based on the assumed conditions and permeability evolution model, different injected pressure and initial methane pressure conditions were set to obtain quantitative results of the competitive adsorption of ScCO₂ and CH₄, permeability changes, and CH₄ production. By obtaining the competitive adsorption relationship between ScCO₂ and CH₄, we analyzed the evolution law of permeability and its impact on CH₄ production. It was found that ScCO₂ has a stronger competitive adsorption capacity, and the competitive adsorption capacity of ScCO₂ and CH₄ is more sensitive to injected pressure. Under two different conditions, it was found that the higher the injected pressure or injected differential pressure, the higher the initial permeability. However, due to the greater sensitivity of the competitive adsorption capacity of ScCO₂ and CH₄ to injected pressure, the greater the injected pressure in the later stage, the greater the decrease in permeability, resulting in a situation where the permeability at an injected pressure of 10 MPa is lower than that at an injected pressure of 8 MPa. A simple comparison was made between gaseous CO₂ and ScCO₂, and it was found that although injecting ScCO₂ has a stronger adsorption swelling capacity that affects permeability changes, its stronger adsorption capacity can effectively displace methane and higher injected pressure, injected temperature, and advantages such as fracturing and extraction that are not yet reflected in the model. This study provides some guidance for numerical simulation of the ScCO₂-ECBM process and the enhancement of coalbed methane extraction.