High mechanical property and hydrophilic electrospun poly amidoxime/poly acrylonitrile composite nanofibrous mats for extraction uranium from seawater

Abstract

Seawater reserves about 4.5 billion tons of uranium, if properly extracted, could be a sustainable green energy resource for hundreds of years, alternating its limited terrestrial ore and reducing the CO₂ emitted from fossil fuels. The current seawater uranium adsorbents suffer neither economically viable nor adsorption efficiency, requiring more development to harvest satisfactorily uranium from seawater. Amidoxime-based fibrous adsorbents are the most promising adsorbents of seawater uranium due to abundant chelating sites. However, they suffer from severe shrinkage and stiffness once they dry, losing porous architecture and mechanical properties. Herein, an economical and scalable two-nozzle electrospinning technology was applied to produce poly amidoxime nanofibers (PAO NFs) supported by Poly acrylonitrile nanofibers (PAN NFs) as composite PAO/PAN nanofibrous mats with high structure stability. These PAO/PAN mats, with rapid wettability and excellent mechanical strength, show promising uranium adsorption capacities of 369.8 mg/g at seawater pH level, much higher than PAO and PAN NFs. The uranium adsorption capacity of the PAO/PAN mat reached 5.16 mg/g after 7 days of circulating (10 ppm uranium) spiked natural seawater. Importantly, the composite mat maintained its fibrous structure after five adsorption-desorption cycles with more than 80 % of its adsorption capacity, confirming its recyclability and stability. Therefore, the composite PAO/PAN mat fulfills the basic requirements for effectively and economically trapping uranium from seawater, which could be a matrix for further development.

Keywords: Composite nanofibrous mat; Electrospinning; High hydrophilic surface; Poly amidoxime; Uranium extraction from seawater.