A copper(I) thiocyanate-based photoresponsive semiconducting 2D coordination polymer

Tomoki Nishiyama; Hirotaka Kitoh-Nishioka; Senku Tanaka; Masahiko Maekawa; Takayoshi Kuroda-Sowa; Masaki Yoshida; Masako Kato; Takashi Okubo

doi:10.1039/d3dt03125j

A copper(I) thiocyanate-based photoresponsive semiconducting 2D coordination polymer

Dalton Trans. 2024 Jan 23;53(4):1445-1448. doi: 10.1039/d3dt03125j.

Authors

Tomoki Nishiyama¹, Hirotaka Kitoh-Nishioka², Senku Tanaka^{2

3}, Masahiko Maekawa^{1

3}, Takayoshi Kuroda-Sowa¹, Masaki Yoshida⁴, Masako Kato⁴, Takashi Okubo^{2

3}

Affiliations

¹ Department of Chemistry, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.
² Department of Energy and Materials, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.
³ Research Institute for Science and Technology, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.
⁴ Department of Applied Chemistry for Environment, School of Biological and Environmental Sciences, Kwansei Gakuin University, 1 Gakuen Uegahara, Sanda, Hyogo 669-1330, Japan.

PMID: 38197251
DOI: 10.1039/d3dt03125j

Abstract

A coordination polymer, [Cu(SCN)(iqi)]_n (iqi = isoquinoline), containing copper(I) thiocyanate and a nitrogen-containing π-conjugated ligand, iqi, has been synthesized and its physical properties were evaluated. This coordination polymer has a two-dimensional (2D) sheet structure consisting of copper(I) thiocyanate and shows photoluminescence derived from ³MLCT and photoconductive properties.