Adaptable strategy for reactivation and recycling of spent S-Zorb adsorbents at the laboratory and pilot scale

Abstract

The spent S-Zorb adsorbents containing Ni and Zn elements are hazardous wastes. It would generate significant economic and environmental benefits to reactivate and recycle these solid wastes through a reactivation strategy. Furthermore, adaptability investigation of this strategy is also indispensable before its industrial application. Herein, the spent S-Zorb adsorbents (Spent-TJ/MM/QD) from different plants were reactivated at laboratory and pilot scale in 3 m³ reactor via an acid-base coupling reactivation strategy. The spent adsorbents exhibit distinct phase compositions and microstructures of active components. Formation of ZnSi₂O₄ and ZnS is the primary reason for abandonment of the Spent-TJ (Spent-MM) and Spent-QD, respectively. The nickel species also exhibit different aggregation extent. Fortunately, the inert zinc and nickel species are respectively converted into ZnO and NiO during the reactivation process. Higher surface area (1.7-4.0 times that of the spent adsorbents) and more acid sites are generated over the reactivated adsorbents. Besides, all the reactivated adsorbents possess similar phase compositions and microstructures. Both the adsorbents reactivated at pilot and laboratory scale exhibit comparable desulfurization activity to fresh ones. The sulfur content of the gasoline desulfurized by the reactivated adsorbents is below 10 μg g^-1, meeting the Euro V legislations. All the results indicate the excellent adaptability and commercial potential of the reactivation strategy. The possible mechanism for the excellent adaptability of the reactivation method was proposed.

Keywords: Adaptability; Pilot scale; Reactivation strategy; Spent S-Zorb adsorbents.