Biomarker and isotopic characteristics of Miocene condensates and natural gases, West Delta deep marine concession, Eastern Mediterranean, Egypt

Naira M Lotfy; Sherif Farouk; Mohammed Hail Hakimi; Fayez Ahmad; Tamer El Shennawy; Mohamed M El Nady; Ahmad Salama; Amr M Shehata

doi:10.1038/s41598-023-50418-4

Biomarker and isotopic characteristics of Miocene condensates and natural gases, West Delta deep marine concession, Eastern Mediterranean, Egypt

Sci Rep. 2024 Jan 2;14(1):235. doi: 10.1038/s41598-023-50418-4.

Authors

Naira M Lotfy¹, Sherif Farouk², Mohammed Hail Hakimi³, Fayez Ahmad⁴, Tamer El Shennawy⁵, Mohamed M El Nady⁶, Ahmad Salama⁷, Amr M Shehata⁶

Affiliations

¹ Exploration Department, Egyptian Petroleum Research Institute (EPRI), Ahmed El Zommor St., Nasr City, Cairo, 11727, Egypt. naira_epri@hotmail.com.
² Exploration Department, Egyptian Petroleum Research Institute (EPRI), Ahmed El Zommor St., Nasr City, Cairo, 11727, Egypt. geo.sherif@hotmail.com.
³ Geology Department, Faculty of Applied Science, Taiz University, 6803, Taiz, Yemen.
⁴ Prince El-Hassan Bin Talal Faculty of Natural Resources and Environment, Department of Earth and Environmental Sciences, The Hashemite University, Zarqa, 13115, Jordan.
⁵ Rashid Petroleum Company, New Maadi Cairo, 11742, Egypt.
⁶ Exploration Department, Egyptian Petroleum Research Institute (EPRI), Ahmed El Zommor St., Nasr City, Cairo, 11727, Egypt.
⁷ Egyptian General Petroleum Corporation, Cairo, Egypt.

Abstract

The Western Delta Deep Marine Concession (WDDM) in the Eastern Mediterranean Sea is one of northern Africa's most recent petroleum-potential regions for gas and condensate exploration. The present study aims to determine the characteristics of the 15 natural gases and 5 associated condensate samples, using molecular compositions and isotopes from the Miocene reservoir rocks in the various wells located in the WDDM. The results of this study are also used to determine the gas-condensate correlation for their probable source rocks as well as the methane-generating mechanisms (i.e., thermogenic or microbiological). Results highlighted in this research reveal that most of the natural gases in WDDM are mainly thermogenic methane gases, with small contributions of biogenic methane gases that were generated from mainly mixed sources, with a high sapropelic organic matter input for biogenic gases. The thermogenic methane gases were formed from secondary oil and oil/gas cracking at the high maturity stage of the gas window. The biogenic gases are also contributed to the Miocene reservoirs, which are formed from the primary cracking of kerogen at low maturity stage by the action of CO₂ bacterial reduction. In addition, the saturated and aromatic biomarker results show that the condensate samples were generated from clay-rich source rocks. This source unit of the Miocene condensates were deposited in a fluvial deltaic environmental setting, containing mixed kerogen type II/III and accumulated during the Jurassic-Cretaceous, as evidenced by the age dating indicators. The properties of the natural gases and associated condensates in the Miocene reservoir rocks suggest that most of the thermogenic methane gases, together with the condensate, are derived primarily from mature Jurassic-Cretaceous source rocks and formed by secondary oil and oil/gas cracking at the gas generation window, as demonstrated by the 1-D basin modelling results highlighted in the prior works. Therefore, most of the natural gases in WDDM are non-indigenous and migrated from more mature Jurassic-Cretaceous source rocks in the nearby Northern Sinai provinces or the deeper sequences in the offshore Nile Delta provinces.