Gas chromatography ion mobility spectroscopy: A rapid and effective tool for monitoring oil oxidation

Fang Cui; Min Liu; Xue Li; Du Wang; Fei Ma; Li Yu; Chundi Hu; Peiwu Li; Liangxiao Zhang

doi:10.1016/j.foodres.2023.113842

Gas chromatography ion mobility spectroscopy: A rapid and effective tool for monitoring oil oxidation

Food Res Int. 2024 Jan:176:113842. doi: 10.1016/j.foodres.2023.113842. Epub 2023 Dec 10.

Authors

Fang Cui¹, Min Liu², Xue Li², Du Wang², Fei Ma², Li Yu², Chundi Hu³, Peiwu Li⁴, Liangxiao Zhang⁵

Affiliations

¹ Key Laboratory of Biology and Genetic Improvement of Oil Crops, Ministry of Agriculture and Rural Affairs, Laboratory of Risk Assessment for Oilseed Products (Wuhan), Ministry of Agriculture and Rural Affairs, Quality Inspection and Test Center for Oilseed Products, Ministry of Agriculture and Rural Affairs, Oil Crops Research Institute, Chinese Academy of Agricultural Sciences, Wuhan 430062, China; Hubei University of Science and Technology, Xianning 437100, China.
² Key Laboratory of Biology and Genetic Improvement of Oil Crops, Ministry of Agriculture and Rural Affairs, Laboratory of Risk Assessment for Oilseed Products (Wuhan), Ministry of Agriculture and Rural Affairs, Quality Inspection and Test Center for Oilseed Products, Ministry of Agriculture and Rural Affairs, Oil Crops Research Institute, Chinese Academy of Agricultural Sciences, Wuhan 430062, China.
³ Hubei University of Science and Technology, Xianning 437100, China.
⁴ Key Laboratory of Biology and Genetic Improvement of Oil Crops, Ministry of Agriculture and Rural Affairs, Laboratory of Risk Assessment for Oilseed Products (Wuhan), Ministry of Agriculture and Rural Affairs, Quality Inspection and Test Center for Oilseed Products, Ministry of Agriculture and Rural Affairs, Oil Crops Research Institute, Chinese Academy of Agricultural Sciences, Wuhan 430062, China; Hubei Hongshan Laboratory, Wuhan 430070, China; Xianghu Laboratory, Hangzhou 311231, China.
⁵ Key Laboratory of Biology and Genetic Improvement of Oil Crops, Ministry of Agriculture and Rural Affairs, Laboratory of Risk Assessment for Oilseed Products (Wuhan), Ministry of Agriculture and Rural Affairs, Quality Inspection and Test Center for Oilseed Products, Ministry of Agriculture and Rural Affairs, Oil Crops Research Institute, Chinese Academy of Agricultural Sciences, Wuhan 430062, China; College of Food Science and Engineering, Nanjing University of Finance and Economics/Collaborative Innovation Center for Modern Grain Circulation and Safety, Nanjing 210023, China; Hubei Hongshan Laboratory, Wuhan 430070, China. Electronic address: zhanglx@caas.cn.

PMID: 38163733
DOI: 10.1016/j.foodres.2023.113842

Abstract

Oil autoxidation is an early process of food deterioration, monitoring oil oxidation is therefore of great significance to ensure food quality and safety. In this study, a detection method of the primary and secondary oxidative products was developed by gas chromatography ion mobility spectrometry (GC-IMS).The secondary oxidative products was analyzed by GC-IMS. Then, the relationships between peroxide values and the contents of secondary oxidative products were investigated by constructing a prediction model of peroxide value of rapeseed oil with the help of secondary oxidative products and chemometrics. The coefficient of determination Q² of the model validation set is 0.96, and the RMSECV is 0.1570 g/100 g. These validation results indicated that secondary oxidative products could also reflect the content of the primary oxidative products. Moreover, 10 characteristic markers related to oxidative rancidity were identified for monitoring edible oil rancidity and oxidative stability.

Keywords: Chemometrics; Freshness; Gas chromatography ion mobility spectrometry (GC-IMS); Oxidative stability; Rapeseed oil.

MeSH terms

Food Quality*
Gas Chromatography-Mass Spectrometry / methods
Ion Mobility Spectrometry* / methods
Peroxides
Rapeseed Oil

Substances

Rapeseed Oil
Peroxides