Study of Chemical Polymerization of Polypyrrole with SDS Soft Template: Physical, Chemical, and Electrical Properties

Thaneeya Samwang; Nozomi Morishita Watanabe; Yukihiro Okamoto; Sira Srinives; Hiroshi Umakoshi

doi:10.1021/acsomega.3c06511

Study of Chemical Polymerization of Polypyrrole with SDS Soft Template: Physical, Chemical, and Electrical Properties

ACS Omega. 2023 Dec 13;8(51):48946-48957. doi: 10.1021/acsomega.3c06511. eCollection 2023 Dec 26.

Authors

Thaneeya Samwang^{1

2}, Nozomi Morishita Watanabe¹, Yukihiro Okamoto¹, Sira Srinives², Hiroshi Umakoshi¹

Affiliations

¹ Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyamacho, Toyonaka 560-8531, Osaka, Japan.
² Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Salaya, Phuttamonthon, 25/25 Phuttamonthon 4 Road, Nakhon Pathom 73170, Thailand.

Abstract

Polypyrrole (PPy) is a conductive polymer known for its biocompatibility and ease of synthesis. Chemically polymerized PPy was synthesized in the presence of sodium dodecyl sulfate (SDS), showing correlations among chemical properties, physical morphology, and electrical properties. Focused synthesis parameters included the pyrrole (Py) concentration, SDS concentration, and ammonium persulfate (APS)/Py ratio. The addition of SDS during chemical polymerization influenced the physical morphology of PPy by altering the self-assembling process via micelle formation, yielding sheet-like morphologies. However, the phenomenon also relied heavily on other synthesis parameters. Varying SDS concentrations within the 0.01 to 0.30 M window produced PPy sheets with no significant difference in optical band gap or physical size. While using 0.10 M SDS, an increase in Py concentration from 0.10 to 0.30 M yielded a larger size of PPy as the morphology changed from sheet-like to irregular shape. The band gap dropped from 2.35 to 1.10 eV, and the conductivity rose from 6.80 × 10^-1 to 9.40 × 10^-1 S/m. With an increase in the APS/Py ratio, the PPy product changed from a random to a sheet-like form. The product provided a larger average size, a decreased band gap, and increased electrical conductivity. Py polymerization in the absence of SDS revealed no significant change in shape or size as the Py concentration increased from 0.10 to 0.30 M; only a sphere-like form was observed, with a large band gap and small conductivity. Results from Raman spectral analysis indicated a correlation between optical band gap, physical morphology, and bipolaron/polaron ratio, mainly at the wavelengths associated with C-C stretching and C-H deformation. The increase in average size was associated with a decrease in band gap and resistance as well as an increase in the bipolaron/polaron ratio. This work indicates a strong correlation between size, morphology, electrical properties, and the bipolaron/polaron ratio of PPy in the presence of SDS.