The development and use of interface materials are essential to the continued advancement of organic solar cells (OSCs) performance. Self-assembled monolayer (SAM) materials have drawn attention because of their simple structure and affordable price. Due to their unique properties, they may be used in inverted devices as a modification layer for modifying ZnO or as a hole transport layer (HTL) in place of typical poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) in conventional devices. In this work, zinc oxide (ZnO) is modified using five structurally similar SAM materials. This resulted in a smoother surface, a decrease in work function, a suppression of charge recombination, and an increase in device efficiency and photostability. In addition, they can introduced asfor hole extraction layer between the active layer and MoO3 , enabling the use of the same material at several functional layers in the same device. Through systematic orthogonal evaluation, it is shown that some SAM/active layer/SAM combinations still offered device efficiencies comparable to ZnO/SAM, but with improved device' photostability. This study may provide recommendations for future SAM material's design and development as well as a strategy for boosting device performance by using the same material across both sides of the photoactive layer in OSCs.
Keywords: modification layer; organic solar cells; photostability; self-assembled monolayer.
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