Mercury cyanide complexes and their relevance as environmental contaminants

Abstract

This review addresses the formation and relevance of mercury cyanide complexes as environmental contaminants. Gold extraction is traditionally carried out through the process of mercury amalgamation (Hg) due to its simplicity and low cost. However, this process is inefficient, capturing only about 30% of the gold present in the processed material. Additionally, mercury is toxic, mobile, and capable of accumulating in aquatic ecosystems, leading to its prohibition in several countries. As an alternative, cyanidation has been widely used in gold extraction. However, the frequent combination of Hg amalgamation with cyanidation can result in the formation of mercury cyanide complexes, which can be released into local water bodies, potentially impacting human health and the environment. This article reviews the existing knowledge of these complexes and highlights the remaining gaps in understanding their environmental behavior. It also emphasizes the need to address concerns related to the formation of these complexes and seek solutions to minimize their negative impacts. Furthermore, the article highlights the lack of updates in the literature regarding the impacts of cyanidation and the limited availability of comprehensive information on the topic. It is essential to conduct updated research in this area to advance knowledge and promote safer and more responsible practices in the mining industry.

Keywords: Aquatic ecosystems; Cyanidation; Gold extraction; Mercury amalgamation.