Over the past few decades, Janus materials have drawn much interest owing to the combination of two different functionalities on the opposite sides. Janus nano-objects (JNOs) with asymmetric polymer brushes are one unique material of them, which consist of a polymeric or inorganic core and asymmetric polymer chains coated on the core. Combining the properties of nanomaterials, asymmetric structures and flexible polymer brushes, hairy JNOs have shown great potential in interfacial compatibilization, interfacial catalysis, oil-water separation and drug delivery. This review summarizes recent progress in the preparation strategies of JNOs with asymmetric polymer brushes via self-assembly or grafting strategies, as well as their applications in interfacial engineering, biomedicine and other aspects. Finally, the outlook and challenges of this direction are discussed.
Keywords: Block copolymer; Grafting; Janus materials; Polymer brushes; Self-assembly.
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