Synergistic effect from combined use of scrap-recycling slag and hydrated lime to stabilize Pb and Zn in highly contaminated soil

Abstract

For the soil in an area which has been repeatedly chosen as one of the 10 most polluted places in the world, stabilization of Pb and Zn was assessed in batch, incubation, and column experiments. Single and combined amendment of scrap-recycling slag (Slag-R), charcoal, coal ash, hydrated lime, and basic oxygen furnace (BOF) slag were applied for the stabilization. Notably, the combined amendment of Slag-R and hydrated lime exhibited superior stabilization efficiencies than the individual use of all stabilizing agents and combined use of charcoal and hydrated lime. The combined amendment of Slag-R and hydrated lime decreased Pb levels by 92-99% and Zn levels by 63-88% in the incubation experiments and by 75% and 89-93%, respectively, in the column experiments. In particular, the combined amendment showed a synergistic effect for Pb stabilization because a higher pH enhanced sorption onto the slag and because sorption onto Fe (hydr)oxides of the sorbent possibly helped to remove Pb. Zinc had a relatively lower sorption tendency, so it was mainly controlled by the pH increase from hydrated lime. Although the addition of hydrated lime was very effective in stabilizing high concentrations of Pb and Zn, the dosage should be controlled carefully because excessively high pH redissolves Pb and Zn as anions.

Keywords: Adsorption; Fe (hydr)oxides; Soil remediation; Synergistic effect; pH increase.