All-Solid-State Supercapacitors Based on Cobalt Magnesium Telluride Microtubes Decorated with Tellurium Nanotubes

ChemSusChem. 2024 Apr 8;17(7):e202301009. doi: 10.1002/cssc.202301009. Epub 2024 Jan 26.

Abstract

Magnesium (Mg) has received very little exploration on its importance in the realm of battery-type energy storage technologies. They are abundantly present in seawater, and if successfully extracted and utilized in energy storage systems, it could lead to the long-term advancement of human civilization. Here, we fabricated an all-solid-state supercapacitor (ASSSC) using tellurium nanotubes decorated cobalt magnesium telluride microtubes (Te NTs@CoMgTe MTs) clad on nickel foam (NF). Owing to the unique mixed phase hierarchical structure, Te NTs@CoMgTe MTs showcases some advancement in energy storage performance. When tested in a three-electrode system, multiphasic hybrid of elemental Te and metal tellurides, Te NTs@CoMgTe MTs outperforms the monometallic telluride owing to the strong synergistic interaction effect triggered from conductive three components and delivers a long-life span performance up to 15,000 cycles. The fabricated Te NT@CoMgTe MT//AC solid-state device exhibits a maximum areal capacity of 59.2 μAh cm-2 (56.3 mAh g-1) at a current density of 6 mA cm-2 with a maximum energy density of 42.2 Wh kg-1 (46.5 μWh cm-2) at a power density of 6857.1 W kg-1 (7574.6 μW cm-2). The performance of the device is rigid even at different bending angles (0 to 180°) which validates the extensibility of the process for future applications.

Keywords: Solid-state supercapacitor; conductivity; flexible; microtubes; telluride.