Bromate (BrO3-), a worldwide regulated by-product after ozone disinfection, is often detected in bromide-containing water, and has a strict limit of 10 μg L-1 in potable water. BrO3- degradation by advanced reduction processes (ARPs) has gained much attention because of efficient removal and easy integration with ultraviolet disinfection (UV at 254 nm). In the vacuum UV (VUV, 185/254 nm)/sulfite system, the elimination kinetics of BrO3- increased by 9-fold and 15-fold comparing with VUV alone and UV/sulfite system. This study further demonstrated the hydrated electron (eaq-) works as the dominant species in BrO3- degradation in alkaline solution, while in the acidic solution the H• became a secondary reactive species besides eaq-. Hence, the influences of pH, sulfite concentration, dissolved gas and water matrix on effectiveness of degradation kinetics of BrO3- was explored in details. With increasing pH, the proportion of SO32- species increased and even became the major ones, which also correlated well with the kobs (min-1) of BrO3- degradation. The stability of eaq- also climbs with increasing pH, while that of H• drops significantly. Higher sulfite dosage favored a more rapid degradation of BrO3-. The presence of dissolved oxygen inhibited BrO3- removal due to the scavenging effect of O2 toward eaq- and transformed VUV/sulfite-based ARP to an advanced oxidation process (AOP), which was ineffective for BrO3- removal. BrO3- removal was inhibited to varying degrees after anions (e.g., bicarbonate (HCO3-), chloride (Cl-), nitrate (NO3-)) and humic acid (HA) being added.
Keywords: Advanced reduction process; Disinfection byproduct; Hydrated electron; Reactive species; Vacuum UV.
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