ZIF-8 decorated cellulose acetate mixed matrix membrane: An efficient approach for textile effluent treatment

Abstract

The textile industry is the second largest water-intensive industry and generates enormous wastewater. The dyes and heavy metals present in the textile effluent, even at their lower concentrations, can cause an adverse effect on the environment and human health. Recently, mixed matrix membranes have gained massive attention due to membrane property enhancement caused by incorporating nanofillers/additives in the polymer matrix. This current study examines the efficacy of ZIF-8/CA membrane on dye removal and treatment of real-time textile industry effluent. Initially, ZIF-8 nanoparticles were synthesized using a probe sonicator. The XRD, FT-IR, and SEM analysis confirmed the formation of crystalline and hexagonal facet ZIF-8 nanoparticles. The ZIF-8 nanoparticles were dispersed into a cellulose acetate matrix, and a membrane was prepared using the "phase inversion method." The membrane was characterized using FT-IR and SEM analysis, which endorse incorporating ZIF-8 into the polymer matrix. Later, the efficacy of the ZIF-8/CA membrane was verified by dye removal studies. The dye removal studies on crystal violet, acid red 13, and reactive black 5 reveal that the membrane is ∼85% efficient in dye removal, and the studies were further extended to real-time textile effluent treatment. The studies on textile effluent prevail that ZIF-8/CA membrane is also proficient in removing chemical oxygen demand (COD) ∼70%, total organic carbon (TOC) ∼80%, and heavy metals such as lead, chromium, and cadmium from textile wastewater and proved to be efficient in treating the textile effluent.

Keywords: Cellulose acetate; Dye removal; Mixed matrix membrane; Nanofillers; Ultrasound; ZIF-8.