All solid-state batteries (ASSBs) are regarded as one of the promising next-generation energy storage devices due to their expected high energy density and capacity. However, failures due to unrestricted growth of lithium dendrites (LDs) have been a critical problem. Moreover, the understanding of dendrite growth inside solid-state electrolytes is limited. Since the dendrite process is a multi-physical field coupled process, including electrical, chemical, and mechanical factors, no definitive conclusion can summarize the root cause of LDs growth in ASSBs till now. Herein, the existing works on mechanism, identification, and solution strategies of LD in ASSBs with inorganic electrolyte are reviewed in detail. The primary triggers are thought to originate mainly at the interface and within the electrolyte, involving mechanical imperfections, inhomogeneous ion transport, inhomogeneous electronic structure, and poor interfacial contact. Finally, some of the representative works and present an outlook are comprehensively summarized, providing a basis and guidance for further research to realize efficient ASSBs for practical applications.
Keywords: all solid‐state batteries; electrochemistry; lithium dendrites; solid‐state electrolytes.
© 2023 Wiley‐VCH GmbH.