The neutrally charged silicon-vacancy defect (SiV0) is a colour centre in diamond with spin S = 1, a zero-phonon line (ZPL) at 946 nm and long spin coherence, which makes it a promising candidate for quantum network applications. For the proper performance of such colour centres, all of them must have identical optical characteristics. However, in practice, there are factors that influence each individual centre. One of these factors is non-uniform isotope composition for both carbon atoms in diamond lattice and silicon atoms of dopant. In this work, we studied the isotopic shifts of SiV0 centres for CVD-grown epitaxial layers of isotopically enriched 12C and 13C diamonds, as well as for diamond with natural isotope composition but doped only with one isotope of Si (28Si, 29Si and 30Si). The detected shift was 1.60 meV for 12C/13C couple and 0.33 meV for 28Si/29Si and 29Si/30Si couples, which are close to the previously obtained values of the isotopic shift for the negatively charged silicon vacancy (SiV-), which indicates a similar model of interaction with the environment for these two charge states of the SiV colour centres. This article is part of the Theo Murphy meeting issue 'Diamond for quantum applications'.
Keywords: SiV0; diamond; doping; isotopic shift; optical absorption; silicon-vacancy.