Impact of nanoplastics on membrane scaling and fouling in reverse osmosis desalination process

Abstract

Nanoplastics (NPs) are a prevalent type of emerging pollutant in marine environment. However, their fouling behavior and impact on reverse osmosis (RO) membrane performance remain unexplored. We investigated the relationship between polystyrene (PS), one of the most abundant NPs, with silica scaling and humic acid (HA) fouling in RO. The results demonstrated that the surface potential of NPs played an important role in the combined scaling and fouling process. Compared with the negatively charged NPs (original PS and carboxyl group modified PS, PS-COOH), the amino-functionalized PS (PS-NH₂) with positive surface charge significantly accelerated membrane scaling/fouling and induced a synergistic water flux decline, due to the strong electrostatic attraction between PS-NH₂, foulants, and the membrane surface. The amino groups acted as binding sites, which promoted the heterogeneous nucleation of silica and adsorption of HA, then formed stable composite pollutants. Thermodynamic analysis via isothermal titration calorimetry (ITC) further confirmed the spontaneous formation of stable complexes between PS-NH₂ and silicates/HA. Our study provides new insights into the combined NPs fouling with other scalants or foulants, and offers guidance for the accurate prediction of RO performance in the presence of NPs.

Keywords: Combined fouling; Humic acid; Isothermal titration calorimetry; Nanoplastics; Reverse osmosis; Silica scaling.