Microplastic (MP) pollution has emerged as a pressing environmental issue, with its impacts on ecosystems and human health yet to be fully understood. This study aims to investigate the presence and distribution of MPs in the soil of a managed aquifer recharge (MAR) system, built with different reactive barriers of natural materials and irrigated with the secondary effluent of a wastewater treatment plant (WWTP). MPs were extracted from reactive barrier material following an approach based on the density separation of MPs with posterior oxidant digestion, combined with visual and chemical characterisation by Fourier-Transform Infrared Spectroscopy (FTIR). The results revealed the widespread occurrence of MPs in the MAR soil samples. MPs concentration in the different barrier materials ranged from 60 to 236 n kg-1. The most dominant morphologies were fragments (60%) and fibers (17%), and the most abundant colour was white (51%), followed by transparent MPs (20%). Polypropylene (PP) was detected in all the samples with an abundance of 47%, followed by polyethylene (PE, 34%). The interplay of barrier composition significantly influences the retention of MPs, with compost (T5) and woodchips (T4) exhibiting the most notable retention rates. Remarkably, the outer layers of the reactive barriers display superior retention compared to the deeper layers. The findings of this study demonstrate the good performance of the MAR system in retaining MPs and contribute to the growing body of knowledge on MPs pollution in freshwater systems while providing insights into the dynamics of MPs transport and accumulation in soil. Such information can inform the development of effective wastewater management strategies to mitigate the impacts of these pollutants on water resources and safeguard the environment.
Keywords: Microplastics; Polymer identification; Reactive barriers; Retention; Wastewater; Water quality.
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