Assembly of dysprosium(III) cubanes in a metal-organic framework with an ecu topology and slow magnetic relaxation

Dong Shao; Yi Wan; Jiong Yang; Zhijun Ruan; Junlun Zhu; Le Shi

doi:10.1039/d3dt03137c

Assembly of dysprosium(III) cubanes in a metal-organic framework with an ecu topology and slow magnetic relaxation

Dalton Trans. 2023 Nov 28;52(46):17114-17118. doi: 10.1039/d3dt03137c.

Authors

Dong Shao¹, Yi Wan¹, Jiong Yang², Zhijun Ruan¹, Junlun Zhu¹, Le Shi³

Affiliations

¹ Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, P. R. China. shaodong@nju.edu.cn.
² Department of Chemistry, Southern University of Science and Technology (SUSTech), Shenzhen 518055, P. R. China.
³ Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China.

PMID: 37987159
DOI: 10.1039/d3dt03137c

Abstract

A dysprosium(III) metal-organic framework constructed using dysprosium(III) cubanes as secondary building units has been reported to exhibit field-induced slow magnetic relaxation behavior and an unprecedented ecu topology, which is the first example of an 8-connected Ln-cubane-based framework material and a rare Dy₄-MOF showing slow magnetic relaxation.