Tungsten Material Behavior under H2, D2, and He Plasma Interaction Conditions in the Framework of Fusion-Relevant Studies

Materials (Basel). 2023 Oct 25;16(21):6853. doi: 10.3390/ma16216853.

Abstract

In the current study, bulk tungsten material surfaces are exposed to hydrogen, deuterium, and helium plasmas in the radiofrequency domain (13.56 MHz) at an input power of 250 W using the hollow-cathode configuration. The ejected material is collected on titanium substrates at various distances (from 6 mm up to 40 mm). Therefore, the exposed tungsten materials are investigated for surface changes (blister occurrence, dust formation, or nano-structuration), along with the crystallinity, depending on the plasma's exposure times (from 30 min up to 120 min for each plasma type). Also, the collected materials are analyzed (morphological, structural, and statistical investigations) for dust and dust film-like appearance. Plasma discharges are analyzed using two methods: optical emission spectroscopy, and single Langmuir probes, to emphasize the nature of the used plasmas (cold discharges, ~2 eV), along with the presence of tungsten emission (e.g., WI 406.31 nm, WI 421.31 nm) during the plasma lifetime. By using a dedicated protocol, a method was established for obtaining fusion-relevant tungsten surfaces in the hydrogen and deuterium plasma discharges. By using the implemented method, the current paper introduces the possibility of obtaining a new tungsten morphology, i.e., the dandelion-like shape, by using helium plasma, in which the W18O49 compound can be found.

Keywords: blisters; crystallinity; dust; hydrogen, deuterium, and helium plasmas; nanostructured surface; plasma–tungsten surface interaction; tungsten surfaces.