Ultrasonic processing of WO3 nanosheets integrated Ti3C2 MXene 2D-2D based heterojunctions with synergistic effects for enhanced water splitting and environmental remediation

Ultrason Sonochem. 2023 Dec:101:106681. doi: 10.1016/j.ultsonch.2023.106681. Epub 2023 Nov 7.

Abstract

This article describes a straightforward chemical procedure that involves hydrothermal and ultrasonic treatments to create a new 2D/2D ultrathin WO3/Ti3C2 heterojunctions. The features of the fabricated heterojunctions were characterized and examined by field emission electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), optical absorption spectroscopy (UV-Vis). By photodegrading an organic dye under the influence of visible light, the photocatalytic degradation capabilities of the heterojunctions were also investigated. The performance of WO3/Ti3C2 was superior to that of bare WO3, with a removal rate of 94% and a kinetic rate constant (k) that was approximately 3 times that of WO3. The creation of 2D/2D heterojunction was observed to encourage the spatial charge separation and increase the surface reactive sites, to result with the increased photocatalytic activity in WO3/Ti3C2 heterojunction. The photocurrent values discovered through photoelectrochemical studies further indicated Ti3C2's active function in enhancing water-splitting performance. The impedance analysis examined by an electrochemical method revealed that heterojunctions might be helpful in accelerating the migration of charges quickly to get the outcomes seen.

Keywords: Heterojunctions; MXenes; Oxides; Photocatalytic; Photoelectrochemical.