Applying bottom ash as an alternative Fenton catalyst for effective removal of phenol from aqueous environment

Abstract

In this study, coal bottom ash from a thermoelectric plant was tested as an alternative Fenton catalyst for phenol degradation in water. The effect of operating parameters such as initial pH, catalyst dosage and H₂O₂ concentration were evaluated. The characterization results indicated that the material has a mesoporous structure, with active species (Fe) well distributed on its surface. Under the optimal reaction conditions (6 mM H₂O₂, 1 g L^-1 of catalyst and pH = 3), 98.7% phenol degradation efficiency was achieved in 60 min, as well as 71.6% TOC removal after 150 min. Hydroxyl radical was identified as the main oxidizing agent involved on the cleavage of the phenol molecule. After four consecutive reuse cycles, phenol degradation efficiency was around 80%, indicating good reusability and stability of the catalyst. Therefore, the obtained results demonstrated that the bottom ash presents remarkable activity for application in the Fenton reaction towards phenol degradation.

Keywords: Bottom ash; Characterization; Fenton; Mechanism; Phenol.