Efficient and durable electrocatalysts fabricated by using nanosized nonprecious-metal-based materials have attracted considerable attention for use in the oxygen evolution reaction (OER). Understanding performance disparities and structure-property relationships of various nonprecious-metal-based nanostructures is crucial for optimizing their applications. Herein, CoP nanoparticles encompassed within a CoFeP shell (named CoP/CoFeP) are fabricated. The mesoporous CoFeP shell enables effective mass transport, affords abundant active sites, and ensures the accessibility of hybrid interfaces between CoP and CoFeP. Therefore, encased CoP/CoFeP nanocubes exhibit excellent OER catalytic activity with an overpotential of 266 mV at a current density of 10 mA cm-2 in alkaline media, superior to reference hollow CoFeP nanocubes and commercial RuO2. Experimental characterization and theoretical calculations show that the encased structure of CoP/CoFeP with a rich Fe-doped shell enables electronic interactions between CoP and CoFeP, as well as accelerates structural reconstruction that exposes more active sites, yielding an enhanced OER performance. This study aims to inspire further work on nonprecious-metal catalysts with tailored nanostructures and electronic properties for the OER.
Keywords: encased structure; mesoporous materials; oxygen evolution reaction; synergistic effect; transition-metal phosphides.