Effect of Temperature, Pressure, and Type of Gas Injected on the Formation and Decay of Mineral Oil-Based Foams

ACS Omega. 2023 Oct 16;8(43):40321-40340. doi: 10.1021/acsomega.3c04565. eCollection 2023 Oct 31.

Abstract

In three-phase gravity separators used in gas and oil production, foaming can occur by either depressurization or injection of gas in the equipment. This formed foam can be harmful, causing various problems such as liquid carry-over, gas carry-under, decreased capacity, and difficulty in level measurement. The mechanism of foam formation by gas injection in separators motivated the present study. Thus, this work proposes the analysis of the influence of certain physical-chemical parameters such as temperature (20-40 °C), pressure (1-10 bar), and types of gases (nitrogen and methane) on the formation of the column and stability of the foam formed, in ISO14 mineral oil + sodium laureth sulfate + water, through gas injection in separator conditions. To carry out this analysis, an experimental apparatus was designed and assembled consisting of a transparent foam formation cell of 0.5 m height and 5 cm internal diameter. Parameters such as foamability, foaminess, and the collapse curve were also evaluated to characterize the foam formed. In addition, simplified models of foam formation and decay by gas injection were proposed based on models already available in the literature, which were validated with the experimentally obtained results. The experimental results showed good agreement when compared to the literature, referring to the behavior of temperature (higher temperature, lower stability), pressure (higher pressure, higher stability), and type of injected gas (dependency on solubility). In addition, maximum errors of 26% (in height) and 11% (decay phase) were obtained for the formation and decay models, respectively.