Perfluoroalkyl and polyfluoroalkyl substances (PFASs) represent a category of persistent and hazardous organic pollutants extensively prevalent across aquatic environments. The combination of adsorption and photocatalytic degradation has been identified as an effective approach for removing trace amounts of PFASs from water. Among the various materials explored for this purpose, metal-organic frameworks (MOFs) have structural solid tunability, and suitable modification methods could endow them with rich adsorption capabilities and excellent photocatalytic performance, which has potential for applications involving the treatment of trace, multi-chain-length PFASs in water. The research within this realm is currently in its nascent phase, and a holistic knowledge of modification methods can provide a comprehensive framework for future studies. Therefore, this review intends to (1) summarize the mechanism underlying the adsorption and photocatalytic removal of PFASs by MOFs; (2) present various modification methods aimed at enhancing the adsorption and photocatalytic performance of MOFs in alignment with the goal mentioned above; (3) provide an outlook on the prospects of utilizing MOFs for PFASs removal based on current trends and data. Ultimately, the findings from these studies will contribute to advancing knowledge in this area and facilitate the development of effective strategies for addressing PFASs contamination in water systems.
Keywords: Adsorption; Goal-oriented; Metal-organic frameworks (MOFs); Perfluoroalkyl and polyfluoroalkyl substances (PFASs); Photocatalysis.
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