Curved aromatic molecules are attractive electronic materials, where an additional internal strain uniquely modifies their structure, aromaticity, dynamics, and optical properties. Helicenes are examples of such twisted conjugated systems. Herein, we analyze the photoinduced dynamics in different stereoisomers of a hexapole helicene by using nonadiabatic excited-state molecular dynamics simulations. We explore how changes in symmetry and structural distortion modulate the intramolecular energy redistribution. We find that distinct helical assembly leads to different rigid distorted structures that in turn impact the nonradiative energy relaxation and ultimately formation of the self-trapped exciton. Subsequently, the value of the twisting angles relative to the central triphenylene core structure controls the global molecular aromaticity and electronic localization during the internal conversion process. Our work sheds light on how the future synthesis of novel curved aromatic compounds can be directed to attain specific desired electronic properties through the modulation of their twisted aromaticity.