Hydrothermal liquefaction of municipal sludge and its products applications

Abstract

Hydrothermal liquefaction (HTL) is an effective medium-temperature, high-pressure thermochemical process to dispose municipal sludge (MS), and biocrude (a crude bio-oil) is its main product. Many efforts are continued extensively to improve conversion efficiency and to promote industrial application of this technology. This work focuses on critical influencing factors (e.g., reaction temperature, residence time, atmosphere, solvent, catalyst, and pretreatment) and fundamental transformation mechanisms of main components (i.e., lipids, proteins, and carbohydrates) in MS HTL. It also analyzes migration behavior of heavy metals during MS HTL, which can provide a reference for subsequent recovery of nutrients from HTL products. Moreover, the applications of MS HTL products are systematically expounded, and potential challenges and opportunities are highlighted as well. It is necessary to develop advanced methods of catalyst recovery and innovative biocrude upgrading methods so as to reduce HTL investment and operating costs. Reusing aqueous phase and solid phase products as reaction medium and catalyst carrier separately after MS HTL is feasible to realize resource utilization of MS. This information can provide valuable guidance to promote MS HTL industrialization.

Keywords: Aqueous phase; Biocrude; Hydrochar applications; Hydrothermal liquefaction; Municipal sludge.