Heteroatom doping to reconfigure the electronic structure of heterogeneous catalysts is expected to lead to the development of advanced oxidation water purification materials with superior performance and greater stability. Herein, a series of catalysts with different elemental doping was developed by a simple and environmentally friendly one-step self-propagating combustion method to remove Tetracycline (TC). After S-doping, the normalized kinetic constant of TC was significantly increased from 30.49 to 159.41 min-1M-1 within 30 min, which is even higher than most recent heterogeneous catalysts. The prepared S-doped NiCo2O4 (NCO-S) exhibits an extremely promising catalytic performance for oxidation (92.8 %) and mineralization (65.9 %) of TC in a wide pH range (3-11). The resistance to interference is excellent for inorganic ions and even in real water samples. Quenching experiments, electron paramagnetic resonance (EPR), and electrochemical analyses demonstrated that the non-radical oxidation pathway, including electron transfer and 1O2, dominated the degradation process after S doping. It is speculated that possible intermediates and toxicological studies are discussed, finding that the overall degradation process is moving towards low toxicity to reveal prospects for large-scale applications. This work not only provides a way to remove TC, but may also inspire the design of more efficient and stable materials for water treatment and other applications.
Keywords: Advanced oxidation; Heteroatom doping; NiCo(2)O(4); Synergism; Tetracycline; Toxicity assessment.
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