Field investigation of the transport and attenuation of fugitive methane in shallow groundwater around an oil and gas well with gas migration

Tiago A Morais; Neil A Fleming; Dinu Attalage; Bernhard Mayer; K U Mayer; M Cathryn Ryan

doi:10.1016/j.scitotenv.2023.168246

Field investigation of the transport and attenuation of fugitive methane in shallow groundwater around an oil and gas well with gas migration

Sci Total Environ. 2024 Jan 15:908:168246. doi: 10.1016/j.scitotenv.2023.168246. Epub 2023 Nov 2.

Authors

Tiago A Morais¹, Neil A Fleming², Dinu Attalage², Bernhard Mayer², K U Mayer³, M Cathryn Ryan²

Affiliations

¹ Department of Department of Earth, Energy and Environment, University of Calgary, Calgary, Alberta, Canada. Electronic address: tamorais@ucalgary.ca.
² Department of Department of Earth, Energy and Environment, University of Calgary, Calgary, Alberta, Canada.
³ Department of Earth, Ocean and Atmospheric Science, University of British Columbia, Vancouver, British Columbia, Canada.

PMID: 37918755
DOI: 10.1016/j.scitotenv.2023.168246

Abstract

'Fugitive' or 'stray' gas migration from deeper formations due to well bore integrity failure has prompted concern regarding environmental impacts. Unintended methane (CH₄) migration can increase greenhouse gas emissions and affect groundwater quality in the critical zone. Although the CH₄ transport in shallow aquifers has been investigated at experimental injection sites, no intensive groundwater studies have been published around an oil and gas well that has been leaking for a significant period of time. In this field study, groundwater samples were collected from sixteen groundwater monitoring wells (1.25 m below ground surface) installed around a suspended oil and gas well with decadal scale gas migration (estimated ~0.2 m³/day). Stray CH₄ distribution and preferential pathways in the shallow groundwater zone were evaluated though high-resolution profiling of equivalent concentrations of hydrocarbon gases (C1-C6; >85 % CH₄ at the study site) and bulk formation electrical conductivity to 6.0 m below ground surface. The highest dissolved CH₄ concentration (0.074 mmol/L or 1.18 mg/L) in groundwater (1.25 m bgs) was observed immediately downgradient (1.25 m) of the oil and gas well head. Similarly, high-resolution profiling data also revealed the occurrence of relatively high CH₄ concentrations in shallow groundwater along the groundwater flow direction and below fine-grained layers up to 10 m distance from the well head. Microbial DNA analysis from groundwater showed significant community shifts, with the highest relative abundance and diversity of methanotrophs observed in the vicinity of the oil and gas well. This study supports findings from experimental injection and laboratory studies, which also found that significant CH₄ transport i) dominantly occurs in the groundwater flow direction, and ii) laterally as free phase below fine-grained layers. The occurrence of CH₄ concentrations below saturation after more than two decades of gas migration suggests limited impacts have occurred in the shallow subsurface investigated.

Keywords: Fugitive methane; Fugitive natural gases; Gas migration; Greenhouse gas emissions; MiHPT profiling; Shallow aquifers.