The design and synthesis of electrically conductive coordination polymers (CPs) are of special interest due to their applications in the fabrication of many environmentally benign emerging technologies, such as molecular wires, photovoltaic cells, light emitting diodes (LEDs), field effect transistors (FETs) and Schottky barrier diodes (SBDs). Owing to their structural flexibility, easy functionality and adjustable energy levels, CPs are promising candidates for providing a better pathway for superior charge transport. Again, the utilization of visible light as an external stimulus to control and manoeuvre the electrical properties of the CPs is exceptionally motivating for the development of many optoelectronic devices, such as photodetectors, photo-switches, photodiodes and chemiresistive sensors. The applications of such materials in devices will solve questions regarding the energy crisis and environmental concerns. This study provides an overview of the recent advances in the development of photo-responsive CPs and the possibility of their application in developing optoelectronic devices. In this regard, a thorough literature survey was performed and the studies related to the fabrication of photosensitive conducting CPs for applications in optoelectronic devices are listed.