The industrial implementation of covalent adaptable networks hinges on the delicate task of achieving rapid bond exchange activation at specific temperatures while ensuring a sufficiently slow exchange at working temperatures to avoid irreversible deformation. In this pursuit, latent catalysts offer a potential solution, allowing for spatiotemporal control of dynamic exchange in vitrimer networks. However, the irreversible nature of their activation has led to undesired creep deformation after multiple cycles of reprocessing. In this work, we demonstrate that a tetraphenylborate tetramethyl guanidinium salt (TPB:TMG) undergoes a reversible thermal dissociation, releasing free TMG. This thermally reversible organocatalyst can be readily introduced as an additive in industrially relevant materials such as disulfide-containing polyurethane networks (PU) that undergo disulfide exchange in the presence of a base catalyst. In contrast with a free-base-catalyzed process, we demonstrate the dual benefit of adding the thermally reversible TPB:TMG in preventing creep at lower temperatures and also enabling reprocessability of disulfide-containing PU networks at elevated temperatures. The remarkable reversibility of this thermally activated catalyst allows for multiple reprocessing cycles while effectively maintaining a creep-free state at service temperature.