This paper presents a simple method of obtaining polyamide 6 fibres modified with acetanilide and copper ions. During the spinning of the fibres with the additives applied, a partial reduction of CuSO4 to Cu2+ and Cu+ ions occurs, which is observed as a change in the blue colour of the prepared polyamide granulate to the grey-brown colour of the formed fibres. CuMPs obtained as a result of the salt reduction should give the obtained fibres bioactive properties. Three types of microorganisms were selected to assess the microbiological activity of the obtained fibres, i.e., Gram-positive Staphylococcus aureus and Gram-negative Pseudomonas aeruginosa and Escherichia coli. The fibres have antibacterial activity against Gram-positive and Gram-negative bacteria. The largest inhibition zones were obtained for the Gram-positive bacteria Staphylococcus aureus, ranging from 1.5 to 4.5 mm, depending on the concentration of CuMPs. The morphology of the fibres' surfaces was examined by means of scanning electron microscopy (SEM) and optical microscopy (OM). The changes in the polymer structure chemistry are studied by Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray structure studies (WAXS and SAXS) and an energy-dispersive spectroscopy (EDS) analysis. The newly obtained bioactive polyamide fibres can be used in many areas, including medicine, clothing and environmental protection for the production of filters.
Keywords: PA6; acetanilide; additives; antibacterial activity; copper sulphate; fibres; structural analysis.