Although superhydrophobic surfaces have various promising applications, their fabrication methods are often limited to 2D plane surfaces that are vulnerable to abrasion and have limited adhesion to the substrate. Herein, an ultraviolet (UV) curable ink with bulk superhydrophobicity, consisting of poly(dimethylsiloxane) (PDMS) resins, hydrophobic silica, and solvent (porogen), was successfully developed for UV-assisted direct write printing processing. After UV curing of the ink followed by solvent evaporation, the generated porous structure cooperates with silica particles to form a self-similar and hierarchical structure throughout the bulk material, which can keep its original morphology even after cyclic abrasion (over 1000 times) and thus exhibits durable superhydrophobicity. With this unique ink, UV-assisted direct write printing can not only create 2D superhydrophobic surfaces on various substrates (e.g., paper and wire mesh) but also fabricate self-supporting 3D superhydrophobic objects for various applications such as waterproofing and oil-water separation. The printed objects exhibited a stable superhydrophobicity against liquid corrosion and mechanical damage. In addition, the 3D printing approach can be used to optimize the oil-water separation performance of the superhydrophobic porous materials by tuning the pore size, thus presenting promising applications.
Keywords: 3D printing; PDMS; UV-curable; hierarchical structure; superhydrophobicity.