In this work, WO3 nanorod-based aggregates and WO3 nano-shuttles were constructed by a facile hydrothermal route. The structure, morphology, element composition and valence state of the formed WO3 samples were characterized using different testing instruments. As the active anode for lithium-ion batteries, the WO3 nano-shuttle electrode can deliver a reversible specific capacity of 614.7 mA h g-1 after 300 cycles at a current density of 500 mA g-1. The excellent electrochemical properties indicate that WO3 nano-shuttles are a prospective anode candidate for high performance lithium-ion batteries.