A Doped Lanthanide-Based Coordination Polymer Exhibiting High Relative Sensitivity to Ratiometric Luminescent Thermometers at 440 K

Ming-Yu Ye; Ming-Xuan Zhang; Qiao-Fei Xu; La-Sheng Long; Lan-Sun Zheng

doi:10.1021/acs.inorgchem.3c02225

A Doped Lanthanide-Based Coordination Polymer Exhibiting High Relative Sensitivity to Ratiometric Luminescent Thermometers at 440 K

Inorg Chem. 2023 Nov 6;62(44):18009-18013. doi: 10.1021/acs.inorgchem.3c02225. Epub 2023 Oct 23.

Authors

Ming-Yu Ye¹, Ming-Xuan Zhang¹, Qiao-Fei Xu¹, La-Sheng Long¹, Lan-Sun Zheng¹

Affiliation

¹ State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

PMID: 37870376
DOI: 10.1021/acs.inorgchem.3c02225

Abstract

Ratiometric luminescent thermometers with excellent performance often require the luminescent materials to possess high thermal stability and relative sensitivity (S_r). However, such luminescent materials are very rare, especially in physiological (298-323 K) and high-temperature (>373 K) regions. Here we report the synthesis and luminescent property of [Tb_0.995Eu_0.005(pfbz)₂(phen)Cl] (3), which not only exhibits high S_r in physiological temperature but also has a S_r up to 7.47% K^-1 at 440 K, the largest S_r at 440 K in known lanthanide-based coordination compound luminescent materials.