Adsorption of methyl orange on low-cost adsorbent natural materials and modified natural materials: a review

Int J Phytoremediation. 2024;26(5):639-668. doi: 10.1080/15226514.2023.2259989. Epub 2023 Oct 16.

Abstract

Recently a large number of extensive studies have amassed that describe the removal of dyes from water and wastewater using natural adsorbents and modified materials. Methyl orange dye is found in wastewater streams from various industries that include textiles, plastics, printing and paper among other sources. This article reviews methyl orange adsorption onto natural and modified materials. Despite many techniques available, adsorption stands out for efficient water and wastewater treatment for its ease of operation, flexibility and large-scale removal of colorants. It also has a significant potential for regeneration recovery and recycling of adsorbents in comparison to other water treatment methods. The adsorbents described herein were classified into five categories based on their chemical composition: bio-sorbents, activated carbon, biochar, clays and minerals, and composites. In this review article, we want to demonstrate the capacity of natural and modified materials for dye adsorption which can yield significant improvements to the adsorption capacity of dyes such as methyl orange. In addition, the effect of critical variables including contact time, initial methyl orange concentration, dosage of adsorbent, pH, temperature and mechanism on the adsorption efficiency will be covered as part of this literature review.

Keywords: Adsorption mechanism; anionic dye; biomaterials; dye removal; wastewater.

Plain language summary

The novelty of this review article describes the utility of various natural and modified materials employed to remove methyl orange (MO) from water, wastewater and aqueous solutions. Natural sorbents are very popular adsorbents because the majority of them are affordable and readily accessible in terms of addressing key challenges concerning water security that are relevant to MO adsorption processes.This review is significant since it will be useful in guiding researchers on the selection of an adsorbent that would be suitable for MO adsorption. Furthermore, our findings provide a basis for researchers interested in the design of composite adsorbents based on the selection of constituent components.

Publication types

  • Review

MeSH terms

  • Adsorption
  • Azo Compounds*
  • Biodegradation, Environmental
  • Coloring Agents
  • Hydrogen-Ion Concentration
  • Kinetics
  • Wastewater*
  • Water Pollutants, Chemical*

Substances

  • Wastewater
  • methyl orange
  • Water Pollutants, Chemical
  • Coloring Agents
  • Azo Compounds