Stability and Structural Analysis Using Small-Angle Neutron Scattering for Foam of Homogeneous Polyoxyethylene-Type Nonionic Surfactants with Multibranched Chains

Shiho Yada; Mizuho Kuroda; Masashi Ohno; Toshinari Koda; Tomokazu Yoshimura

doi:10.1021/acs.langmuir.3c02424

Stability and Structural Analysis Using Small-Angle Neutron Scattering for Foam of Homogeneous Polyoxyethylene-Type Nonionic Surfactants with Multibranched Chains

Langmuir. 2023 Oct 31;39(43):15355-15361. doi: 10.1021/acs.langmuir.3c02424. Epub 2023 Oct 16.

Authors

Shiho Yada^{1

2}, Mizuho Kuroda¹, Masashi Ohno³, Toshinari Koda³, Tomokazu Yoshimura¹

Affiliations

¹ Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoyanishi-machi, Nara 630-8506, Japan.
² Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan.
³ Nissan Chemical Corporation, 5-1, Nihonbashi 2-chome, Chuo-ku, Tokyo 103-6119, Japan.

PMID: 37844330
DOI: 10.1021/acs.langmuir.3c02424

Abstract

Small-angle neutron scattering can provide insight into the microstructure of the surfactant-stabilized foam. In this study, small-angle neutron scattering in combination with other techniques was employed to determine the microstructure of the foams stabilized using novel homogeneous polyoxyethylene (EO) alkyl ether-type nonionic surfactants with multibranched double chains (bC₇-bC₉EO₁₂). Similarly, homogeneous EO-type nonionic surfactants with linear double chains (C₈-C₈EO₁₂) and a linear single chain (C₁₈EO₁₂) were used. bC₇-bC₉EO₁₂ and C₈-C₈EO₁₂ surfactants with branched hydrophobic chains or double chains increased the foam stability and suppressed the draining. Furthermore, they formed rod-like micelles, and C₁₈EO₁₂ formed spherical micelles in the bulk solution. The foam film containing the plateau border contained micelles identical with those found in the bulk solution. For bC₇-bC₉EO₁₂ and C₈-C₈EO₁₂, the average radius of the bubbles immediately after foaming was of the order of hundreds of μm. Finally, these radii grew to the order of thousands of μm. Thus, a significant correlation was observed between the micellar structure and the stability of these foams.