Unveiling the Structural Characteristics of Intergrowth Zeolites Synthesized in the Presence of Isopropylimidazolium-Based Cations and Fluoride Anions

Kingsley Christian Kemp; Alvaro Mayoral; Suk Bong Hong

doi:10.1021/jacs.3c08700

Unveiling the Structural Characteristics of Intergrowth Zeolites Synthesized in the Presence of Isopropylimidazolium-Based Cations and Fluoride Anions

J Am Chem Soc. 2023 Oct 25;145(42):23300-23307. doi: 10.1021/jacs.3c08700. Epub 2023 Oct 13.

Authors

Kingsley Christian Kemp¹, Alvaro Mayoral², Suk Bong Hong¹

Affiliations

¹ Center for Ordered Nanoporous Materials Synthesis, Division of Environmental Science and Engineering, POSTECH, Pohang 37673, Korea.
² Instituto de Nanociencia y Materiales de Aragon (INMA), Spanish National Research Council (CSIC), Universidad de Zaragoza, 12, Calle de Pedro Cerbuna, 50009 Zaragoza, Spain.

PMID: 37831968
DOI: 10.1021/jacs.3c08700

Abstract

Here, we present the synthesis of RTH/ITE and MEL/MFI intergrowth zeolites using 2-isopropylimidazolium-based cations as organic structure-directing agents (OSDAs) in concentrated fluoride media and their local structural properties. Phase selectivity in the synthesis of zeolite intergrowths was found to differ according to the concentration of OSDA cations and fluoride anions in the synthesis mixture as well as to the type of OSDA employed. Molecular modeling results suggest that the crystallization of intergrowth zeolites in fluoride media may be kinetically rather than thermodynamically controlled, as in ordered zeolites. C_s-corrected STEM analysis of MEL/MFI crystals synthesized at HF/OSDA = 2.0 in the presence of 2-isopropyl-1,3-dipropylimidazolium ions as an OSDA indicates the existence of previously unobserved MEL-MFI intergrowth along the [100] direction, leading to a partial blockage of MEL 10-ring channels.