An efficient cerium dioxide incorporated nickel cobalt phosphide complex as electrocatalyst for All-pH hydrogen evolution reaction and overall water splitting

Dongxiao Li; Zhimin Guo; Ruihuan Zhao; Hao Ren; Yubiao Huang; Yu Yan; Wei Cui; Xin Yao

doi:10.1016/j.jcis.2023.09.144

An efficient cerium dioxide incorporated nickel cobalt phosphide complex as electrocatalyst for All-pH hydrogen evolution reaction and overall water splitting

J Colloid Interface Sci. 2024 Jan;653(Pt B):1725-1742. doi: 10.1016/j.jcis.2023.09.144. Epub 2023 Oct 4.

Authors

Dongxiao Li¹, Zhimin Guo¹, Ruihuan Zhao¹, Hao Ren¹, Yubiao Huang¹, Yu Yan¹, Wei Cui¹, Xin Yao²

Affiliations

¹ School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, PR China.
² School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, PR China; Binzhou Institute of Technology, Binzhou 256606, PR China; National Engineering Laboratory for VOCs Pollution Control Material & Technology Research Center for Environment Material and Pollution Control Technology, University of Chinese Academy of Sciences, Beijing 100049, PR China. Electronic address: yaox@ucas.ac.cn.

PMID: 37827011
DOI: 10.1016/j.jcis.2023.09.144

Abstract

Transition metal phosphides (TMPs) have been considered as potential electrocatalysts with adjustable valence states, metal characteristics, and phase diversity. However, it is necessary but remains a major challenge to obtain efficient and durable TMPs catalysts, which can realize efficiently for not only all-pH hydrogen evolution reaction (HER), but also oxygen evolution reaction (OER). Hence, cerium dioxide incorporated nickel cobalt phosphide growth on nickel foam (CeO₂/NiCoP) is fabricated by hydrothermal and phosphating reaction. CeO₂/NiCoP shows excellent activity for all-pH HER (overpotentials of 48, 58 and 72 mV in alkaline, neutral and acidic solution at the current density of 10 mA cm^-2), and has a small OER overpotential (231 mV @ 10 mA cm^-2). Moreover, the voltage of overall water splitting in alkaline solution and simulated seawater electrolyte is only 1.46 and 1.41 V (10 mA cm^-2), respectively, coupled with outstanding operational stability and corrosion resistance. Further mechanism research shows that CeO₂/NiCoP possesses rich heterointerfaces, which serves more exposed active sites and possesses a promising superhydrophilic and superaerophobic surface. Density functional theory calculations manifest that CeO₂/NiCoP has appropriate energy for intermediates of reactions. This work provides a deep insight into the CeO₂/NiCoP catalyst for high-performance water/seawater electrolysis.

Keywords: Bifunctional electrocatalyst; Density functional theory; Electronic structure regulation; Heterointerface; Superaerophobic; Superhydrophilic.