Yttrium-modified drinking water treatment residue for efficient phosphorus removal: efficacy, mechanism, and reproducibility

Environ Sci Pollut Res Int. 2023 Nov;30(51):111611-111626. doi: 10.1007/s11356-023-30159-7. Epub 2023 Oct 11.

Abstract

The excessive presence of phosphate can cause eutrophication in water bodies. Yttrium has an extremely high affinity for phosphorus and is capable of forming stable complexes at low concentrations. Moreover, limitations in the resourcefulness of drinking water treatment residues were observed. In this study, a highly efficient phosphorus removal adsorbent (RJDWTR@Y) was prepared by calcination-alkali leaching-yttrium-loaded composite modification employing domestic drinking water treatment residue as raw material. And the effects of multiple factors on phosphate adsorption by RJDWTR@Y were examined. The results illustrated that the maximum adsorption capacity of the RJDWTR@Y for phosphate was 319.76 mg/g, with the chemical reaction of the multilayer as the predominant adsorption process. The adsorption mechanism is electrostatic gravitational force and the inner sphere complexation effect. RJDWTR@Y was effective against interference even at high concentrations of the coexisting anion. After five cycles, the desorption efficiency of phosphate was 75.11%. Filling the fixed bed with the material can efficiently remove phosphorus from the flowing liquid. The synthesis of RJDWTR@Y and the results of the study indicated that it has good application prospects. In addition to efficiently removing phosphorus, it can also recycle waste and achieve sustainability.

Keywords: Adsorption; Isotherm, Kinetic model; Phosphorus; Wastewater.

MeSH terms

  • Adsorption
  • Drinking Water*
  • Hydrogen-Ion Concentration
  • Kinetics
  • Phosphates / chemistry
  • Phosphorus / chemistry
  • Reproducibility of Results
  • Wastewater
  • Water Pollutants, Chemical* / chemistry
  • Yttrium

Substances

  • Phosphorus
  • Drinking Water
  • Yttrium
  • Wastewater
  • Phosphates
  • Water Pollutants, Chemical