A modified three-electrode system was utilized with a correlated ion-capture film that is functional to changes in soil carbonate moieties to determine an understudied pool of soil carbon that is vital toward holistic carbon sequestration─carbonous soil minerals (CSM). This composite sensor was tested on soils with varying carbonate contents using cyclic voltammetry, chromatocoulometry (DC-based), and electrochemical impedance spectroscopy to determine signal output as a function of increasing dose. To determine the in-field capability, a portable potentiostat device was integrated into a probe head setup that could be inserted into soil for testing. The results from these experiments showed a linearity of R2 > 0.97 and a measurable sensing range from 0.01% (100 ppm) to 1% (10 000 ppm). Therefore, a first-of-a-kind in-soil sensor system was developed for determining carbonate content in real soil samples using electrochemistry that can be tested in-field to survey the field-deployable and point-of-use capability of the system.
Keywords: carbon sequestration tracking; electrochemical impedance spectroscopy; electrochemical sensor; mineral carbon; soil carbon monitoring; soil inorganic carbon; soil sensor.