(Z)-Benzyl 2-(5-methyl-2-oxoindolin-3-yl-idene)hydrazinecarbodi-thio-ate

Mohd Abdul Fatah Abdul Manan; David B Cordes; Aidan P McKay; Mohd Fazli Mohammat; Mohd Fadhlizil Fasihi Mohd Aluwi; Nor Saliyana Jumali

doi:10.1107/S2414314623007824

(Z)-Benzyl 2-(5-methyl-2-oxoindolin-3-yl-idene)hydrazinecarbodi-thio-ate

IUCrdata. 2023 Sep 12;8(Pt 9):x230782. doi: 10.1107/S2414314623007824. eCollection 2023 Sep.

Authors

Mohd Abdul Fatah Abdul Manan¹, David B Cordes², Aidan P McKay², Mohd Fazli Mohammat³, Mohd Fadhlizil Fasihi Mohd Aluwi⁴, Nor Saliyana Jumali⁵

Affiliations

¹ Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia.
² EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, United Kingdom.
³ Organic Synthesis Research Laboratory, Institute of Science, Universiti Teknologi MARA, 42300 Bandar Puncak Alam, Selangor, Malaysia.
⁴ Centre for Bio-aromatic Research, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang, Kuantan, Pahang, Malaysia.
⁵ Department of Chemistry, Kuliyyah of Science, International Islamic University Malaysia, 25200 Bandar Indera Mahkota, Kuantan, Pahang, Malaysia.

Abstract

The title compound, C₁₇H₁₅N₃OS₂ was obtained from the condensation reaction of S-benzyl-dithio-carbazate and 5-methyl-isatin. In the solid-state, the mol-ecule adopts a Z configuration with the 5-methyl-isatin and di-thio-carbazate groups located on the same side of the C=N bond, involving an intra-molecular N-H⋯O hydrogen bond.

Keywords: 5-methylisatin; Z configuration; crystal structure; dithiocarbazate; hydrogen bonding.

Grants and funding

Funding for this research was provided by: Universiti Teknologi MARA (grant No. 600–RMC/SRC/5/3(043/2020)).