Single-atom catalysts (SACs) are regarded as promising non-noble-metal alternatives for the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells due to their high atom utilization efficiency and excellent catalytic properties. However, the insufficient long-term stability issues of SACs under the working conditions seriously hinder their practical application. In this perspective, the recent progress of SACs with optimized ORR catalytic activity is first reviewed. Then, the possible degradation mechanisms of SACs in the ORR process and effective strategies for improving their ORR durability are summarized. Finally, some challenges and opportunities are proposed to develop stable single-atom-based ORR electrocatalysts in the future.
Keywords: metal−nitrogen−carbon materials; oxygen reduction reaction; proton exchange membrane fuel cells; single-atom catalysts; stability.