A mini review of current studies on metal-organic frameworks-incorporated composite solid polymer electrolytes in all-solid-state lithium batteries

Abstract

All-solid-state lithium batteries (ASSLBs) using solid polymer electrolytes (SPEs) are believed to be future next-generation batteries aiming to replace high-risk traditional batteries using liquid electrolytes, which have a wide application range in portable electronic devices, portable power supplies, and especially in electric vehicles. Moreover, the appearance of SPEs can overcome the electrolyte leakage and flammability problems in conventional lithium-ion batteries. Nevertheless, ASSLBs still face some limitations due to the low ionic conductivity of solid-state electrolytes (SSEs) at room temperature and the poor contact electrode/electrolyte interface, which can be solved by suitable strategies. Currently, the research strategies of metal-organic frameworks that can be incorporated into solid polymer electrolytes offer a remarkable method for producing uniform solid polymer electrolytes that have good electrode/electrolyte contact interfaces and high ionic conductivity. Herein, the updates of current studies about metal-organic framework-incorporated composite solid polymer electrolytes are discussed in this mini-review.

Keywords: All-solid-state lithium batteries; Electrochemistry; Energy storage; Metal-organic frameworks; Solid polymer electrolytes.